It is known to strongly influence the kinetics of diffusion-controlled bimolecular reactions in liquids. |
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The bimolecular rate constants for these reactions are of several orders of magnitude less than diffusion controlled. |
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Specific bimolecular interactions are central to virtually all biological processes. |
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The rate of a reaction with a bimolecular rate law depends on the concentration of two species or the square of the concentration of one species. |
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The reactive collision of more than two molecules at the exact time is unlikely and can be represented as the sequence of bimolecular collisions. |
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On a theoretical point of view, the understanding of enzyme reactions is hardly reducible to elementary bimolecular reactions. |
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We are aware that a palindromic circle could form by a bimolecular reaction. |
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We were able to eliminate this heterogeneity in our samples to obtain a simpler two-phase form for the bimolecular kinetics. |
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The Stern-Volmer plot of these solutions is linear, and the bimolecular reaction rate constant agrees with previous observations. |
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We expect that our cell will be useful for observing the pressure dependence of bimolecular interactions on the single molecule level. |
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At the high concentrations used in this experiment, it is expected that very small signals would be observed from the bimolecular formation of the encounter complex. |
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Understanding the molecular mechanisms of unimolecular and bimolecular misfolding may lead to advances in biomedicine and in protein production improvements. |
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The bimolecular quenching rate constants are less than that of diffusion controlled and decrease as the one-electron reduction potential of the donor radical increases. |
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Basic assumptions were that all elementary reactions in the pathway were bimolecular and that the reacting species were distributed homogeneously. |
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Initial contact will be through a conventional bimolecular binding and occur at a rate proportional to the concentration of freely diffusing molecules. |
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In this case the precursors are mixed just before entering the deposition chamber and the heat of the chamber encourages a gas phase bimolecular reaction. |
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The fundamental difference between the transition states in the bimolecular and unimolecular mechanisms is the degree of covalent bonding between the nucleophile and the substrate in the transition state. |
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In addition to his day job as a scientist, he has faced down the complexity and isolation intrinsic to the scientific analysis of bimolecular structure by creating beautiful paintings of cellular interiors. |
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This bimolecular mechanism occurs with a wide range of structures. |
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A method of forming a bimolecular lipid planar bilayer membrane, comprising the step of immersing a substrate having on the surface of at least one side thereof a long-chain hydrocarbon group, in a suspension of liposome. |
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The degree of structural variation of telomeric G4-structures is high, as they are capable of forming tetramolecular, bimolecular, or unimolecular structures. |
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Refolding of mature subtilisin BPN' is extremely slow unless catalyzed by the independently expressed prosegment, leading to a bimolecular complex. |
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